This is too general a question and no answer is going to be definate.
The majority of people porting heads and doing vavle jobs are stupid people. The outcome of a 3+ angle valve job depends on who is doing it.
The most frequently used valve job that I have seen would have to be a 30-45-60(competition my a$$). This valve job is old and should be retired to the trash can, but you will still see many cylinder head machinists using it(why?)Because they are stupid).
You can get cutters in any angle you want. Depending on the head and intended usage of the head determines what angles will work best for you.
On most 23* chevy heads I have had the best results using a 37-45-58. This will increase the mid-lift flow(.300"-.500").
45* seats are usually for lower lifts in the .600" and below range. While 55* seats are for the higher lifts .600"+.
When you hear of 5,6,7 angle valve jobs this is when the angles cut on the valve are added to the angles cut on the seat. This in no way will hurt, crack or warp anything.
Example:
6 Angle valve job.
SEAT.....................Valve
Top........ 37*..........Face.....45*
Seat....... 45*..........Backut...30*
1st bottom. 58*
2nd bottom. 75*
The widths of the cuts are also very important. They should be in this range:
SEAT Intake Width
Top.........(.060"-.080")
Seat........(street).060") - (race).040")
1st bottom..(.090"-.100")
2nd bottom..(cut this until 1st bottom reacehes the 1st bottom reaches .090"-.100")
SEAT Exhaust Width
Top.........(same)
Seat........(street).070")(race).060")(turbo).080")
VALVE Intake
Face........(.060"-.070")
Backut......(.060"-.080")
VALVE Exhaust
Face........(.060"-.080")(depending on usage)
Backut......(no backcut unless face is wider than .120")
The power increase depends on the quality of the head and how much it is flowing. Also on how good or bad the head is. Vortec heads you might see a 15-20cfm increase on a fully ported set. While on some Lb4,L35 you might see an increase of 10cfm.
I would not recommend taking your head to anyone unless they are well known for being great head porters. Ask questions also.
Ryan